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Table 4 Analytical results of the solutions before and after the 2, 44 days lasting alteration experiments (200 °C, 260 °C)

From: The Muschelkalk aquifer of the Molasse basin in SW-Germany: implications on the origin and development of highly saline lithium-rich brines in calcareous hydrothermal reservoirs

 

Initial solution

Solution after 200 °C experiment

Solution after 260 °C experiment

Electr. Cond. (mS cm−1)

139

142

140

pH (at 25 °C)

5.52

7.22

7.38

pH (in situ)

5.52

7.45

7.79

Na

44,600

46,200

45,400

K

9.8

57

30

Ca

 < 0.01

99

315

Mg

 < 0.02

0.5

3.9

Fe

 < 0.0004

0.056

0.989

Al

 < 0.0004

0.127

0.042

Si

–

39

77

Li

0.078

0.062

0.081

Rb

0.025

0.041

0.124

Cs

0.0014

0.072

0.022

Sr

 < 0.00002

0.493

1.051

Ba

0.0029

8.736

18.350

Cl

66,500

68,800

68,000

HCO3

–

268

873

  1. In situ pH-values were calculated with the code PHREEQC using the LLNL data base (Parkhurst and Appelo 2013). Concentrations are given in mg kg−1